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Umpolung carbonyls enable direct allylation and olefination of carbohydrates

Mother Nature has its own arts to build a vast number of carbohydrates; however, there is still a lack of tools for selective functionalization of native carbohydrates through C─C bond formation. Such a long-standing challenge for the synthetic community lies into the intrinsic problems related to t...

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Detalles Bibliográficos
Autores principales: Kan, Jian, Chen, Zhangpei, Qiu, Zihang, Lv, Leiyang, Li, Chenchen, Li, Chao-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8906572/
https://www.ncbi.nlm.nih.gov/pubmed/35263121
http://dx.doi.org/10.1126/sciadv.abm6840