Tetracyclic silaheterocycle formed through a pericyclic reaction cascade including a two-fold intramolecular C–C bond activation

Reductive debromination of the tribromoamidosilane 2 gave the tetracyclic silaheterocycle 3 through a unique reaction cascade involving unprecedented two-fold intramolecular cycloaddition by transient silylenes. Experimental and computational analyses of the reaction mechanism allowed the identifica...

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Detalles Bibliográficos
Autores principales: Helmer, Joschua, Pakkanen, Olli J., Gendy, Chris, Hepp, Alexander, Tuononen, Heikki M., Lips, Felicitas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8908502/
https://www.ncbi.nlm.nih.gov/pubmed/35195653
http://dx.doi.org/10.1039/d2cc00298a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8908502/
https://www.ncbi.nlm.nih.gov/pubmed/35195653
http://dx.doi.org/10.1039/d2cc00298a

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