Stable Carbenes as Structural Components of Partially Saturated Sulfur-Containing Heterocycles

Recently, an unusual elongation of the C-S bond was observed experimentally for some sulfur-containing heterocycles. Using a superior ab initio (SCS-MP2/cc-pVTZ) level of theory, we showed that the phenomenon can be explained by a contribution of a donor–acceptor adduct of a carbene with an unsatura...

Descripción completa

Detalles Bibliográficos
Autores principales: Rozhenko, Alexander B., Horbenko, Yuliia S., Kyrylchuk, Andrii A., Zarudnitskii, Evgenij V., Mykhaylychenko, Sergiy S., Shermolovich, Yuriy G., Grafov, Andriy V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8911733/
https://www.ncbi.nlm.nih.gov/pubmed/35268558
http://dx.doi.org/10.3390/molecules27051458

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8911733/
https://www.ncbi.nlm.nih.gov/pubmed/35268558
http://dx.doi.org/10.3390/molecules27051458

Ejemplares similares