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Stable Carbenes as Structural Components of Partially Saturated Sulfur-Containing Heterocycles

Recently, an unusual elongation of the C-S bond was observed experimentally for some sulfur-containing heterocycles. Using a superior ab initio (SCS-MP2/cc-pVTZ) level of theory, we showed that the phenomenon can be explained by a contribution of a donor–acceptor adduct of a carbene with an unsatura...

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Detalles Bibliográficos
Autores principales:	Rozhenko, Alexander B., Horbenko, Yuliia S., Kyrylchuk, Andrii A., Zarudnitskii, Evgenij V., Mykhaylychenko, Sergiy S., Shermolovich, Yuriy G., Grafov, Andriy V.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2022
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8911733/ https://www.ncbi.nlm.nih.gov/pubmed/35268558 http://dx.doi.org/10.3390/molecules27051458

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