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Photoinduced bond oscillations in ironpentacarbonyl give delayed synchronous bursts of carbonmonoxide release

Early excited state dynamics in the photodissociation of transition metal carbonyls determines the chemical nature of short-lived catalytically active reaction intermediates. However, time-resolved experiments have not yet revealed mechanistic details in the sub-picosecond regime. Hence, in this stu...

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Detalles Bibliográficos
Autores principales: Banerjee, Ambar, Coates, Michael R., Kowalewski, Markus, Wikmark, Hampus, Jay, Raphael M., Wernet, Philippe, Odelius, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8921231/
https://www.ncbi.nlm.nih.gov/pubmed/35288563
http://dx.doi.org/10.1038/s41467-022-28997-z