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Photoinduced bond oscillations in ironpentacarbonyl give delayed synchronous bursts of carbonmonoxide release
Early excited state dynamics in the photodissociation of transition metal carbonyls determines the chemical nature of short-lived catalytically active reaction intermediates. However, time-resolved experiments have not yet revealed mechanistic details in the sub-picosecond regime. Hence, in this stu...
Autores principales: | Banerjee, Ambar, Coates, Michael R., Kowalewski, Markus, Wikmark, Hampus, Jay, Raphael M., Wernet, Philippe, Odelius, Michael |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8921231/ https://www.ncbi.nlm.nih.gov/pubmed/35288563 http://dx.doi.org/10.1038/s41467-022-28997-z |
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