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Halobenzene Clathrates of the Porous Metal–Organic Spin-Crossover Framework [Fe(tvp)(2)(NCS)(2)](n). Stabilization of a Four-Step Transition

[Image: see text] Here we show that the porous metal–organic spin crossover (SCO) framework [Fe(tvp)(2)(NCS)(2)]@4(CH(3)CN·H(2)O) [1@4(CH(3)CN·H(2)O)] is an excellent precursor material for the systematic synthesis, via single-crystal to single-crystal transformation, of a series of halobenzene clat...

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Detalles Bibliográficos
Autores principales: Orellana-Silla, Alejandro, Valverde-Muñoz, Francisco Javier, Muñoz, M. Carmen, Bartual-Murgui, Carlos, Ferrer, Sacramento, Real, José Antonio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8924922/
https://www.ncbi.nlm.nih.gov/pubmed/35235314
http://dx.doi.org/10.1021/acs.inorgchem.2c00014