Monomeric Triphosphinoboranes: Intramolecular Lewis Acid–Base Interactions between Boron and Phosphorus Atoms

[Image: see text] Herein, we present the synthesis of the first fully characterized monomeric triphosphinoboranes. The simple reaction of boron tribromide with 3 equiv of bulky lithium phosphide tBu(2)PLi yielded triphosphinoborane (tBu(2)P)(3)B. Triphosphinoboranes with diversified phosphanyl subst...

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Detalles Bibliográficos
Autores principales: Ordyszewska, Anna, Szynkiewicz, Natalia, Chojnacki, Jarosław, Grubba, Rafał
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8924927/
https://www.ncbi.nlm.nih.gov/pubmed/35220712
http://dx.doi.org/10.1021/acs.inorgchem.1c03618

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8924927/
https://www.ncbi.nlm.nih.gov/pubmed/35220712
http://dx.doi.org/10.1021/acs.inorgchem.1c03618

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