Three-Component Coupling of Arenes, Ethylene, and Alkynes Catalyzed by a Cationic Bis(phosphine) Cobalt Complex: Intercepting Metallacyclopentenes for C–H Functionalization

[Image: see text] A cobalt-catalyzed intermolecular three-component coupling of arenes, ethylene, and alkynes was developed using the well-defined air-stable cationic bis(phosphine) cobalt(I) complex, [(dcype)Co(η(6)-C(7)H(8))][BAr(F)(4)] (dcype = 1,2-bis(dicyclohexylphosphino)ethane; BAr(F)(4) = B[...

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Detalles Bibliográficos
Autores principales: Whitehurst, William G., Kim, Junho, Koenig, Stefan G., Chirik, Paul J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8931730/
https://www.ncbi.nlm.nih.gov/pubmed/35245039
http://dx.doi.org/10.1021/jacs.1c12646

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8931730/
https://www.ncbi.nlm.nih.gov/pubmed/35245039
http://dx.doi.org/10.1021/jacs.1c12646

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