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Three-Component Coupling of Arenes, Ethylene, and Alkynes Catalyzed by a Cationic Bis(phosphine) Cobalt Complex: Intercepting Metallacyclopentenes for C–H Functionalization
[Image: see text] A cobalt-catalyzed intermolecular three-component coupling of arenes, ethylene, and alkynes was developed using the well-defined air-stable cationic bis(phosphine) cobalt(I) complex, [(dcype)Co(η(6)-C(7)H(8))][BAr(F)(4)] (dcype = 1,2-bis(dicyclohexylphosphino)ethane; BAr(F)(4) = B[...
Autores principales: | Whitehurst, William G., Kim, Junho, Koenig, Stefan G., Chirik, Paul J. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8931730/ https://www.ncbi.nlm.nih.gov/pubmed/35245039 http://dx.doi.org/10.1021/jacs.1c12646 |
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