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Lewis acid protection turns cyanide containing [FeFe]-hydrogenase mimics into proton reduction catalysts
Sustainable sources of hydrogen are a vital component of the envisioned energy transition. Understanding and mimicking the [FeFe]-hydrogenase provides a route to achieving this goal. In this study we re-visit a molecular mimic of the hydrogenase, the propyl dithiolate bridged complex [Fe(2)(μ-pdt)(C...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8939051/ https://www.ncbi.nlm.nih.gov/pubmed/35212328 http://dx.doi.org/10.1039/d1dt03896f |