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Lewis acid protection turns cyanide containing [FeFe]-hydrogenase mimics into proton reduction catalysts

Sustainable sources of hydrogen are a vital component of the envisioned energy transition. Understanding and mimicking the [FeFe]-hydrogenase provides a route to achieving this goal. In this study we re-visit a molecular mimic of the hydrogenase, the propyl dithiolate bridged complex [Fe(2)(μ-pdt)(C...

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Detalles Bibliográficos
Autores principales:	Redman, Holly J., Huang, Ping, Haumann, Michael, Cheah, Mun Hon, Berggren, Gustav
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8939051/ https://www.ncbi.nlm.nih.gov/pubmed/35212328 http://dx.doi.org/10.1039/d1dt03896f

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