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Synergistic Brønsted/Lewis acid catalyzed aromatic alkylation with unactivated tertiary alcohols or di-tert-butylperoxide to synthesize quaternary carbon centers

Dual Brønsted/Lewis acid catalysis involving environmentally benign, readily accessible protic acid and iron promotes site-selective tert-butylation of electron-rich arenes using di-tert-butylperoxide. This transformation inspired the development of a synergistic Brønsted/Lewis acid catalyzed aromat...

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Detalles Bibliográficos
Autores principales: Pan, Aaron, Chojnacka, Maja, Crowley, Robert, Göttemann, Lucas, Haines, Brandon E., Kou, Kevin G. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8943850/
https://www.ncbi.nlm.nih.gov/pubmed/35432882
http://dx.doi.org/10.1039/d1sc06422c