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Sprayed water microdroplets containing dissolved pyridine spontaneously generate pyridyl anions
The anion of pyridine, C(5)H(5)N(−), has been thought to be short lived in the gas phase and was only previously observed indirectly. In the condensed phase, C(5)H(5)N(−) is known to be stabilized by solvation with other molecules. We provide in this study striking results for the formation of isola...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
National Academy of Sciences
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8944249/ https://www.ncbi.nlm.nih.gov/pubmed/35286201 http://dx.doi.org/10.1073/pnas.2200991119 |