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Sustainable Production of Reduced Phosphorus Compounds: Mechanochemical Hydride Phosphorylation Using Condensed Phosphates as a Route to Phosphite

[Image: see text] In pursuit of a more sustainable production of phosphorous acid (H(3)PO(3)), a versatile chemical with phosphorus in the +3 oxidation state, we herein report that condensed phosphates can be employed to phosphorylate hydride reagents under solvent-free mechanochemical conditions to...

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Detalles Bibliográficos
Autores principales: Zhai, Feng, Xin, Tiansi, Geeson, Michael B., Cummins, Christopher C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8949633/
https://www.ncbi.nlm.nih.gov/pubmed/35350608
http://dx.doi.org/10.1021/acscentsci.1c01381