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Stereoisomeric Tris-BINOL-Menthol Bulky Monophosphites: Synthesis, Characterisation and Application in Rhodium-Catalysed Hydroformylation

Four stereoisomeric monoether derivatives, based on axially chiral (R)- or (S)-BINOL bearing a chiral (+)- or (−)-neomenthyloxy group were synthesised and fully characterised by NMR spectroscopy and X-ray crystallography. The respective tris-monophosphites were thereof prepared and fully characteris...

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Detalles Bibliográficos
Autores principales: Felgueiras, Alexandre P., Rodrigues, Fábio M. S., Carrilho, Rui M. B., Cruz, Pedro F., Rodrigues, Vitor H., Kégl, Tamás, Kollár, László, Pereira, Mariette M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8954005/
https://www.ncbi.nlm.nih.gov/pubmed/35335351
http://dx.doi.org/10.3390/molecules27061989