Kinetic Study of the Oxidative Addition Reaction between Methyl Iodide and [Rh(imino-β-diketonato)(CO)(PPh)(3)] Complexes, Utilizing UV–Vis, IR Spectrophotometry, NMR Spectroscopy and DFT Calculations

The oxidative addition of methyl iodide to [Rh(β-diketonato)(CO)(PPh)(3)] complexes, as modal catalysts of the first step during the Monsanto process, are well-studied. The β-diketonato ligand is a bidentate (BID) ligand that bonds, through two O donor atoms (O,O-BID ligand), to rhodium. Imino-β-dik...

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Detalles Bibliográficos
Autores principales: Ferreira, Hendrik, Conradie, Marrigje Marianne, Conradie, Jeanet
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8954617/
https://www.ncbi.nlm.nih.gov/pubmed/35335295
http://dx.doi.org/10.3390/molecules27061931

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8954617/
https://www.ncbi.nlm.nih.gov/pubmed/35335295
http://dx.doi.org/10.3390/molecules27061931

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