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Kinetic resolution of cyclic benzylic azides enabled by site- and enantioselective C(sp(3))–H oxidation

Catalytic nonenzymatic kinetic resolution (KR) of racemates remains one of the most powerful tools to prepare enantiopure compounds, which dominantly relies on the manipulation of reactive functional groups. Moreover, catalytic KR of organic azides represents a formidable challenge due to the small...

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Detalles Bibliográficos
Autores principales: Ye, Pengbo, Feng, Aili, Wang, Lin, Cao, Min, Zhu, Rongxiu, Liu, Lei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8956603/
https://www.ncbi.nlm.nih.gov/pubmed/35338143
http://dx.doi.org/10.1038/s41467-022-29319-z