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Kinetic resolution of cyclic benzylic azides enabled by site- and enantioselective C(sp(3))–H oxidation
Catalytic nonenzymatic kinetic resolution (KR) of racemates remains one of the most powerful tools to prepare enantiopure compounds, which dominantly relies on the manipulation of reactive functional groups. Moreover, catalytic KR of organic azides represents a formidable challenge due to the small...
Autores principales: | Ye, Pengbo, Feng, Aili, Wang, Lin, Cao, Min, Zhu, Rongxiu, Liu, Lei |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8956603/ https://www.ncbi.nlm.nih.gov/pubmed/35338143 http://dx.doi.org/10.1038/s41467-022-29319-z |
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