Stability of the H-cluster under whole-cell conditions—formation of an H(trans)-like state and its reactivity towards oxygen

Hydrogenases are metalloenzymes that catalyze the reversible oxidation of molecular hydrogen into protons and electrons. For this purpose, [FeFe]-hydrogenases utilize a hexanuclear iron cofactor, the H-cluster. This biologically unique cofactor provides the enzyme with outstanding catalytic activiti...

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Detalles Bibliográficos
Autores principales: Lorenzi, Marco, Ceccaldi, Pierre, Rodríguez-Maciá, Patricia, Redman, Holly Jayne, Zamader, Afridi, Birrell, James A., Mészáros, Livia S., Berggren, Gustav
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer International Publishing 2022
Materias:
Original Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8960641/
https://www.ncbi.nlm.nih.gov/pubmed/35258679
http://dx.doi.org/10.1007/s00775-022-01928-5

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8960641/
https://www.ncbi.nlm.nih.gov/pubmed/35258679
http://dx.doi.org/10.1007/s00775-022-01928-5

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