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Stability of the H-cluster under whole-cell conditions—formation of an H(trans)-like state and its reactivity towards oxygen

Hydrogenases are metalloenzymes that catalyze the reversible oxidation of molecular hydrogen into protons and electrons. For this purpose, [FeFe]-hydrogenases utilize a hexanuclear iron cofactor, the H-cluster. This biologically unique cofactor provides the enzyme with outstanding catalytic activiti...

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Detalles Bibliográficos
Autores principales:	Lorenzi, Marco, Ceccaldi, Pierre, Rodríguez-Maciá, Patricia, Redman, Holly Jayne, Zamader, Afridi, Birrell, James A., Mészáros, Livia S., Berggren, Gustav
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Springer International Publishing 2022
Materias:	Original Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8960641/ https://www.ncbi.nlm.nih.gov/pubmed/35258679 http://dx.doi.org/10.1007/s00775-022-01928-5

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