Di- and Tetrameric Molybdenum Sulfide Clusters Activate and Stabilize Dihydrogen as Hydrides

[Image: see text] NaY zeolite-encapsulated dimeric (Mo(2)S(4)) and tetrameric (Mo(4)S(4)) molybdenum sulfide clusters stabilize hydrogen as hydride binding to Mo atoms. Density functional theory (DFT) calculations and adsorption measurements suggest that stabilization of hydrogen as sulfhydryl (SH)...

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Detalles Bibliográficos
Autores principales: Khare, Rachit, Weindl, Roland, Jentys, Andreas, Reuter, Karsten, Shi, Hui, Lercher, Johannes A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8965828/
https://www.ncbi.nlm.nih.gov/pubmed/35373212
http://dx.doi.org/10.1021/jacsau.1c00507

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8965828/
https://www.ncbi.nlm.nih.gov/pubmed/35373212
http://dx.doi.org/10.1021/jacsau.1c00507

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