Cargando…
Di- and Tetrameric Molybdenum Sulfide Clusters Activate and Stabilize Dihydrogen as Hydrides
[Image: see text] NaY zeolite-encapsulated dimeric (Mo(2)S(4)) and tetrameric (Mo(4)S(4)) molybdenum sulfide clusters stabilize hydrogen as hydride binding to Mo atoms. Density functional theory (DFT) calculations and adsorption measurements suggest that stabilization of hydrogen as sulfhydryl (SH)...
| Autores principales: | , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8965828/ https://www.ncbi.nlm.nih.gov/pubmed/35373212 http://dx.doi.org/10.1021/jacsau.1c00507 |