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Charge-State Dependence of Proton Uptake in Polyoxovanadate-alkoxide Clusters
[Image: see text] Here, we present an investigation of the thermochemistry of proton uptake in acetonitrile across three charge states of a polyoxovanadate-alkoxide (POV-alkoxide) cluster, [V(6)O(7)(OMe)(12)](n) (n = 2–, 1–, and 0). The vanadium oxide assembly studied features bridging sites saturat...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8965876/ https://www.ncbi.nlm.nih.gov/pubmed/35293218 http://dx.doi.org/10.1021/acs.inorgchem.1c02937 |