C–Cl Oxidative Addition and C–C Reductive Elimination Reactions in the Context of the Rhodium-Promoted Direct Arylation

[Image: see text] A cycle of stoichiometric elemental reactions defining the direct arylation promoted by a redox-pair Rh(I)–Rh(III) is reported. Starting from the rhodium(I)-aryl complex RhPh{κ(3)-P,O,P-[xant(P(i)Pr(2))(2)]} (xant(P(i)Pr(2))(2) = 9,9-dimethyl-4,5-bis(diisopropylphosphino)xanthene),...

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Detalles Bibliográficos
Autores principales: de las Heras, Laura A., Esteruelas, Miguel A., Oliván, Montserrat, Oñate, Enrique
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8966374/
https://www.ncbi.nlm.nih.gov/pubmed/35368715
http://dx.doi.org/10.1021/acs.organomet.1c00643

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8966374/
https://www.ncbi.nlm.nih.gov/pubmed/35368715
http://dx.doi.org/10.1021/acs.organomet.1c00643

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