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Intramolecular hydrogen transfer in DNA induced by site-selective resonant core excitation

We present experimental evidence for soft X-ray induced intramolecular hydrogen transfer in the protonated synthetic tri-oligonucleotide d((F)UAG) in the gas-phase ((F)U: fluorouracil). The trinucleotide cations were stored in a cryogenic ion trap and exposed to monochromatic synchrotron radiation....

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Detalles Bibliográficos
Autores principales: Wang, Xin, Rathnachalam, Sivasudhan, Zamudio-Bayer, Vicente, Bijlsma, Klaas, Li, Wen, Hoekstra, Ronnie, Kubin, Markus, Timm, Martin, von Issendorff, Bernd, Lau, J. Tobias, Faraji, Shirin, Schlathölter, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8966622/
https://www.ncbi.nlm.nih.gov/pubmed/35297440
http://dx.doi.org/10.1039/d1cp05741c