Temperature triggered alternating copolymerization of epoxides and lactones via pre-sequenced spiroorthoester intermediates

We report the alternating copolymerization of caprolactone and epoxide through the in situ formation of pre-sequenced spiroorthoester monomer. The reaction is catalyzed by the temperature triggered, bifunctional cationic indium complex (±)-[(NN(i)O(tBu))In(CH(2)SiMe(3))][B(C(6)F(5))(4)] (1). 1 can c...

Descripción completa

Detalles Bibliográficos
Autores principales: Jung, Hyuk-Joon, Goonesinghe, Chatura, Mehrkhodavandi, Parisa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8966630/
https://www.ncbi.nlm.nih.gov/pubmed/35432898
http://dx.doi.org/10.1039/d1sc06634j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8966630/
https://www.ncbi.nlm.nih.gov/pubmed/35432898
http://dx.doi.org/10.1039/d1sc06634j

Ejemplares similares