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Temperature triggered alternating copolymerization of epoxides and lactones via pre-sequenced spiroorthoester intermediates

We report the alternating copolymerization of caprolactone and epoxide through the in situ formation of pre-sequenced spiroorthoester monomer. The reaction is catalyzed by the temperature triggered, bifunctional cationic indium complex (±)-[(NN(i)O(tBu))In(CH(2)SiMe(3))][B(C(6)F(5))(4)] (1). 1 can c...

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Detalles Bibliográficos
Autores principales:	Jung, Hyuk-Joon, Goonesinghe, Chatura, Mehrkhodavandi, Parisa
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8966630/ https://www.ncbi.nlm.nih.gov/pubmed/35432898 http://dx.doi.org/10.1039/d1sc06634j

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