α-Branched amines through radical coupling with 2-azaallyl anions, redox active esters and alkenes

α-Branched amines are fundamental building blocks in a variety of natural products and pharmaceuticals. Herein is reported a unique cascade reaction that enables the preparation of α-branched amines bearing aryl or alkyl groups at the β- or γ-positions. The cascade is initiated by reduction of redox...

Descripción completa

Detalles Bibliográficos
Autores principales: Duan, Shengzu, Zi, Yujin, Wang, Lingling, Cong, Jielun, Chen, Wen, Li, Minyan, Zhang, Hongbin, Yang, Xiaodong, Walsh, Patrick J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8966660/
https://www.ncbi.nlm.nih.gov/pubmed/35432903
http://dx.doi.org/10.1039/d2sc00500j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8966660/
https://www.ncbi.nlm.nih.gov/pubmed/35432903
http://dx.doi.org/10.1039/d2sc00500j

Ejemplares similares