DFT insight into asymmetric alkyl–alkyl bond formation via nickel-catalysed enantioconvergent reductive coupling of racemic electrophiles with olefins

A DFT study has been conducted to understand the asymmetric alkyl–alkyl bond formation through nickel-catalysed reductive coupling of racemic alkyl bromide with olefin in the presence of hydrosilane and K(3)PO(4). The key findings of the study include: (i) under the reductive experimental conditions...

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Detalles Bibliográficos
Autores principales: Zhang, Chao-Shen, Zhang, Bei-Bei, Zhong, Liang, Chen, Xiang-Yu, Wang, Zhi-Xiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8966719/
https://www.ncbi.nlm.nih.gov/pubmed/35432909
http://dx.doi.org/10.1039/d1sc05605k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8966719/
https://www.ncbi.nlm.nih.gov/pubmed/35432909
http://dx.doi.org/10.1039/d1sc05605k

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