Lanthanide-mediated tuning of electronic and magnetic properties in heterotrimetallic cyclooctatetraenyl multidecker self-assemblies

The synthesis of a novel family of homoleptic COT-based heterotrimetallic self-assemblies bearing the formula [LnKCa(COT)(3)(THF)(3)] (Ln(iii) = Gd, Tb, Dy, Ho, Er, Tm, and Yb) is reported followed by their X-ray crystallographic and magnetic characterization. All crystals conform to the monoclinic...

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Detalles Bibliográficos
Autores principales: Zhou, Zheng, McNeely, James, Greenough, Joshua, Wei, Zheng, Han, Haixiang, Rouzières, Mathieu, Rogachev, Andrey Yu., Clérac, Rodolphe, Petrukhina, Marina A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8966735/
https://www.ncbi.nlm.nih.gov/pubmed/35432895
http://dx.doi.org/10.1039/d2sc00631f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8966735/
https://www.ncbi.nlm.nih.gov/pubmed/35432895
http://dx.doi.org/10.1039/d2sc00631f

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