Torsional strain inversed chemoselectivity in a Pd-catalyzed atroposelective carbonylation reaction of dibenzothiophenium

A palladium-catalyzed enantioselective ring-opening/carbonylation of cyclic diarylsulfonium salts is reported. In comparison to thioethers, the sulfonium salts displayed high reactivity and enabled the reaction to be performed under mild conditions (room temperature). The steric repulsion of the two...

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Detalles Bibliográficos
Autores principales: Zhang, Qiuchi, Xue, Xiaoping, Hong, Biqiong, Gu, Zhenhua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8966737/
https://www.ncbi.nlm.nih.gov/pubmed/35432889
http://dx.doi.org/10.1039/d2sc00341d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8966737/
https://www.ncbi.nlm.nih.gov/pubmed/35432889
http://dx.doi.org/10.1039/d2sc00341d

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