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Silver-catalyzed site-selective C(sp(3))−H benzylation of ethers with N-triftosylhydrazones

The insertion of carbenes into the α-C–H bonds of ethers represents one of the most powerful approaches to access polysubstituted α-branched ethers. However, intermolecular carbene insertions remain challenging, since current approaches are generally limited to the use of toxic and potentially explo...

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Detalles Bibliográficos
Autores principales: Liu, Zhaohong, Wang, Hongwei, Sivaguru, Paramasivam, Nolan, Steven P., Song, Qingmin, Yu, Weijie, Jiang, Xinyu, Anderson, Edward A., Bi, Xihe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8967862/
https://www.ncbi.nlm.nih.gov/pubmed/35354822
http://dx.doi.org/10.1038/s41467-022-29323-3