Dichotomy of platinum(II) and gold(III) carbene intermediates switching from N- to O-selectivity

Pt(II) and Au(III)-mediated intermolecular divergent annulations of benzofurazans and ynamides highlighted the N- to O-selectivity of tunable metal carbene intermediates. PtCl(2) with a bulky phosphite ligand resulted in the specific synthesis of six-membered quinoxaline N-oxides and successfully su...

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Detalles Bibliográficos
Autores principales: Jin, Hongming, Tong, Wen-Yan, Zhang, Jing, Rudolph, Matthias, Rominger, Frank, Shen, Xu, Qu, Shuanglin, Hashmi, A. Stephen K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8967914/
https://www.ncbi.nlm.nih.gov/pubmed/35354823
http://dx.doi.org/10.1038/s41467-022-29326-0

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8967914/
https://www.ncbi.nlm.nih.gov/pubmed/35354823
http://dx.doi.org/10.1038/s41467-022-29326-0

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