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Dichotomy of platinum(II) and gold(III) carbene intermediates switching from N- to O-selectivity
Pt(II) and Au(III)-mediated intermolecular divergent annulations of benzofurazans and ynamides highlighted the N- to O-selectivity of tunable metal carbene intermediates. PtCl(2) with a bulky phosphite ligand resulted in the specific synthesis of six-membered quinoxaline N-oxides and successfully su...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8967914/ https://www.ncbi.nlm.nih.gov/pubmed/35354823 http://dx.doi.org/10.1038/s41467-022-29326-0 |