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Dichotomy of platinum(II) and gold(III) carbene intermediates switching from N- to O-selectivity

Pt(II) and Au(III)-mediated intermolecular divergent annulations of benzofurazans and ynamides highlighted the N- to O-selectivity of tunable metal carbene intermediates. PtCl(2) with a bulky phosphite ligand resulted in the specific synthesis of six-membered quinoxaline N-oxides and successfully su...

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Detalles Bibliográficos
Autores principales:	Jin, Hongming, Tong, Wen-Yan, Zhang, Jing, Rudolph, Matthias, Rominger, Frank, Shen, Xu, Qu, Shuanglin, Hashmi, A. Stephen K.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2022
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8967914/ https://www.ncbi.nlm.nih.gov/pubmed/35354823 http://dx.doi.org/10.1038/s41467-022-29326-0

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