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Revisiting Reduction of CO(2) to Oxalate with First-Row Transition Metals: Irreproducibility, Ambiguous Analysis, and Conflicting Reactivity

[Image: see text] Construction of higher C(≥2) compounds from CO(2) constitutes an attractive transformation inspired by nature’s strategy to build carbohydrates. However, controlled C–C bond formation from carbon dioxide using environmentally benign reductants remains a major challenge. In this res...

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Detalles Bibliográficos
Autores principales: Marx, Maximilian, Frauendorf, Holm, Spannenberg, Anke, Neumann, Helfried, Beller, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8970009/
https://www.ncbi.nlm.nih.gov/pubmed/35373201
http://dx.doi.org/10.1021/jacsau.2c00005