DFT Mechanistic Insights into Aldehyde Deformylations with Biomimetic Metal–Dioxygen Complexes: Distinct Mechanisms and Reaction Rules

[Image: see text] Aldehyde deformylations occurring in organisms are catalyzed by metalloenzymes through metal–dioxygen active cores, attracting great interest to study small-molecule metal–dioxygen complexes for understanding relevant biological processes and developing biomimetic catalysts for aer...

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Detalles Bibliográficos
Autores principales: Zhao, Ruihua, Zhang, Bei-Bei, Liu, Zheyuan, Cheng, Gui-Juan, Wang, Zhi-Xiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8970012/
https://www.ncbi.nlm.nih.gov/pubmed/35373207
http://dx.doi.org/10.1021/jacsau.2c00014

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8970012/
https://www.ncbi.nlm.nih.gov/pubmed/35373207
http://dx.doi.org/10.1021/jacsau.2c00014

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