Cargando…

DFT Mechanistic Insights into Aldehyde Deformylations with Biomimetic Metal–Dioxygen Complexes: Distinct Mechanisms and Reaction Rules

[Image: see text] Aldehyde deformylations occurring in organisms are catalyzed by metalloenzymes through metal–dioxygen active cores, attracting great interest to study small-molecule metal–dioxygen complexes for understanding relevant biological processes and developing biomimetic catalysts for aer...

Descripción completa

Detalles Bibliográficos
Autores principales:	Zhao, Ruihua, Zhang, Bei-Bei, Liu, Zheyuan, Cheng, Gui-Juan, Wang, Zhi-Xiang
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8970012/ https://www.ncbi.nlm.nih.gov/pubmed/35373207 http://dx.doi.org/10.1021/jacsau.2c00014

Ejemplares similares

Structural insights into the catalytic mechanism of aldehyde-deformylating oxygenases
por: Jia, Chenjun, et al.
Publicado: (2014)

Solvent Isotope Effects on Alkane Formation by Cyanobacterial Aldehyde Deformylating Oxygenase and Their Mechanistic Implications
por: Waugh, Matthew W., et al.
Publicado: (2014)

Insights into Substrate and Metal Binding from the Crystal Structure of Cyanobacterial Aldehyde Deformylating Oxygenase with Substrate Bound
por: Buer, Benjamin C., et al.
Publicado: (2014)

Mechanistic insights into dioxygen activation by a manganese corrole complex: a broken-symmetry DFT study
por: Yu, Jiangfeng, et al.
Publicado: (2021)

Microbial synthesis of propane by engineering valine pathway and aldehyde-deformylating oxygenase
por: Zhang, Lei, et al.
Publicado: (2016)

Structure-oriented substrate specificity engineering of aldehyde-deformylating oxygenase towards aldehydes carbon chain length
por: Bao, Luyao, et al.
Publicado: (2016)

A DFT-based mechanistic proposal for the light-driven insertion of dioxygen into Pt(ii)–C bonds
por: Fernández-Alvarez, Victor M., et al.
Publicado: (2018)

Deformylation reaction-based probe for in vivo imaging of HOCl
por: Wei, Peng, et al.
Publicado: (2017)

Role of Cysteine Residues in the Structure, Stability, and Alkane Producing Activity of Cyanobacterial Aldehyde Deformylating Oxygenase
por: Hayashi, Yuuki, et al.
Publicado: (2015)

Identification of residues important for the activity of aldehyde-deformylating oxygenase through investigation into the structure-activity relationship
por: Wang, Qing, et al.
Publicado: (2017)

Conversion of fatty aldehydes into alk (a/e)nes by in vitro reconstituted cyanobacterial aldehyde-deformylating oxygenase with the cognate electron transfer system
por: Zhang, Jingjing, et al.
Publicado: (2013)

Identification of non-conserved residues essential for improving the hydrocarbon-producing activity of cyanobacterial aldehyde-deformylating oxygenase
por: Kudo, Hisashi, et al.
Publicado: (2019)

Production of Propane and Other Short-Chain Alkanes by Structure-Based Engineering of Ligand Specificity in Aldehyde-Deformylating Oxygenase
por: Khara, Basile, et al.
Publicado: (2013)

Dioxygen Activation by Internally Aromatic Metallacycle: Crystallographic Structure and Mechanistic Investigations
por: Deng, Zhihong, et al.
Publicado: (2020)

Acylation Reactions of Dibenzo‐7‐phosphanorbornadiene: DFT Mechanistic Insights
por: Qu, Zheng‐Wang, et al.
Publicado: (2019)

Comparison of orthologous cyanobacterial aldehyde deformylating oxygenases in the production of volatile C3-C7 alkanes in engineered E. coli
por: Patrikainen, Pekka, et al.
Publicado: (2017)

Deformylation of 5‐Formylcytidine in Different Cell Types
por: Korytiaková, Eva, et al.
Publicado: (2021)

Direct Benzene Hydroxylation with Dioxygen Induced by Copper Complexes: Uncovering the Active Species by DFT Calculations
por: Borrego, Elena, et al.
Publicado: (2022)

Dioxygen Reactivity of Biomimetic Fe(II) Complexes with Noninnocent Catecholate, o-Aminophenolate, and o-Phenylenediamine Ligands
por: Bittner, Michael M., et al.
Publicado: (2014)

Mechanistic insight into the catalytic hydrogenation of nonactivated aldehydes with a Hantzsch ester in the presence of a series of organoboranes: NMR and DFT studies
por: Hamasaka, Go, et al.
Publicado: (2019)

Mechanistic insights into hydroacylation with non-chelating aldehydes
por: Murphy, Stephen K., et al.
Publicado: (2015)

Alkane biosynthesis by Aspergillus carbonarius ITEM 5010 through heterologous expression of Synechococcus elongatus acyl-ACP/CoA reductase and aldehyde deformylating oxygenase genes
por: Sinha, Malavika, et al.
Publicado: (2017)

NATO Advanced Study Institute on the Coordination Chemistry of Metalloenzymes : the Role of Metals in Reactions Involving Water, Dioxygen and Related Species
por: Bertini, I, et al.
Publicado: (1983)

Quinone-catalyzed oxidative deformylation: synthesis of imines from amino alcohols
por: Liu, Xinyun, et al.
Publicado: (2017)

Biochemical and structural characterization of a sphingomonad diarylpropane lyase for cofactorless deformylation
por: Kuatsjah, Eugene, et al.
Publicado: (2023)

Aerobic Metal-Free Dioxygenation of Alkenes with tert-Butyl Nitrite and N-Hydroxylamines
por: Bag, Raghunath, et al.
Publicado: (2017)

Dioxygen Reactivity of Copper(I)/Manganese(II)-Porphyrin Assemblies: Mechanistic Studies and Cooperative Activation of O(2)
por: Li, Runzi, et al.
Publicado: (2022)

Dioxygen, an unexpected carbonic anhydrase ligand
por: Ferraroni, Marta, et al.
Publicado: (2018)

Analysis of an Active Deformylation Mechanism of 5‐Formyl‐deoxycytidine (fdC) in Stem Cells
por: Schön, Alexander, et al.
Publicado: (2020)

Computational Mechanistic Insights on the NO Oxidation Reaction Catalyzed by Non-Heme Biomimetic Cr-N-Tetramethylated Cyclam Complexes
por: Marino, Tiziana, et al.
Publicado: (2019)

Dioxygen and Metabolism; Dangerous Liaisons in Cardiac Function and Disease
por: Angelini, Aude, et al.
Publicado: (2017)

Direct dioxygen evolution in collisions of carbon dioxide with surfaces
por: Yao, Yunxi, et al.
Publicado: (2019)

Dioxygen Activation by a Bioinspired Tungsten(IV) Complex
por: Ćorović, Miljan Z., et al.
Publicado: (2023)

Bio-inspired electron-delivering system for reductive activation of dioxygen at metal centres towards artificial flavoenzymes
por: Roux, Yoann, et al.
Publicado: (2015)

Catalytic two-electron reduction of dioxygen catalysed by metal-free [14]triphyrin(2.1.1)
por: Mase, Kentaro, et al.
Publicado: (2015)

Mechanistic insights into reductive deamination with hydrosilanes catalyzed by B(C(6)F(5))(3): A DFT study
por: Zhou, Miaomiao, et al.
Publicado: (2022)

Ground-state dioxygen undergoes metal-free [3 + 2]-annulations with allenes and nitrosoarenes under ambient conditions
por: Liu, Jinxian, et al.
Publicado: (2017)

Mechanistic Insights into the DABCO-Catalyzed Cloke–Wilson Rearrangement: A DFT Perspective
por: Gallardo-Fuentes, Sebastián, et al.
Publicado: (2023)

Enantio‐ and Regioselective Palladium(II)‐Catalyzed Dioxygenation of (Aza‐)Alkenols
por: Giofrè, Sabrina, et al.
Publicado: (2021)

Coinage Metal-Catalyzed Asymmetric Reactions of ortho-Alkynylaryl and Heteroaryl Aldehydes and Ketones
por: Melot, Romain, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_4r8ccjf5jehnb9ntrb2hh9v2ni