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Mechanistic Insights on the Selectivity of the Tandem Heck–Ring-Opening of Cyclopropyldiol Derivatives

[Image: see text] The preparation of a new class of alkenyl cyclopropyl diols, easily available through a copper-catalyzed carbometalation reaction of cyclopropenes, has enabled the study of key mechanistic aspects of the tandem Heck–cyclopropane ring-opening reaction. Utilizing these substrates con...

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Detalles Bibliográficos
Autores principales: Cohen, Anthony, Kaushansky, Alexander, Marek, Ilan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8970019/
https://www.ncbi.nlm.nih.gov/pubmed/35373195
http://dx.doi.org/10.1021/jacsau.1c00547