Hyper-CEST NMR of metal organic polyhedral cages reveals hidden diastereomers with diverse guest exchange kinetics

Guest capture and release are important properties of self-assembling nanostructures. Over time, a significant fraction of guests might engage in short-lived states with different symmetry and stereoselectivity and transit frequently between multiple environments, thereby escaping common spectroscop...

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Detalles Bibliográficos
Autores principales: Jayapaul, Jabadurai, Komulainen, Sanna, Zhivonitko, Vladimir V., Mareš, Jiří, Giri, Chandan, Rissanen, Kari, Lantto, Perttu, Telkki, Ville-Veikko, Schröder, Leif
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8971460/
https://www.ncbi.nlm.nih.gov/pubmed/35361759
http://dx.doi.org/10.1038/s41467-022-29249-w

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8971460/
https://www.ncbi.nlm.nih.gov/pubmed/35361759
http://dx.doi.org/10.1038/s41467-022-29249-w

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