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Two cyclometalated Pt(ii) complexes showing reversible phosphorescence switching due to grinding-induced destruction and crystallization-induced formation of supramolecular dimer structure
Complexes [Pt(dfppy)(pbdtmi)]PF(6) (1) and [Pt(ppy)(pbdtmi)]PF(6) (2) have been constructed based on dithienylethene-based N^N ligand pbdtmi, showing supramolecular dimer structure in which two coordination cations connect each other through π⋯π stacking interaction. The crystalline state samples of...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8978655/ https://www.ncbi.nlm.nih.gov/pubmed/35424484 http://dx.doi.org/10.1039/d1ra07142d |