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Two cyclometalated Pt(ii) complexes showing reversible phosphorescence switching due to grinding-induced destruction and crystallization-induced formation of supramolecular dimer structure

Complexes [Pt(dfppy)(pbdtmi)]PF(6) (1) and [Pt(ppy)(pbdtmi)]PF(6) (2) have been constructed based on dithienylethene-based N^N ligand pbdtmi, showing supramolecular dimer structure in which two coordination cations connect each other through π⋯π stacking interaction. The crystalline state samples of...

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Detalles Bibliográficos
Autores principales:	Yuan, Qin-Zhen, Wan, Fu-Shun, Shen, Ting-Ting, Cao, Deng-Ke
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2021
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8978655/ https://www.ncbi.nlm.nih.gov/pubmed/35424484 http://dx.doi.org/10.1039/d1ra07142d

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