Role of imine isomerization in the stereocontrol of the Staudinger reaction between ketenes and imines

Computational–experimental analysis has allowed determining that the stereochemistry of the Staudinger reaction between ketenes and imines is strongly associated with the nature of the imine, which affects the two steps of the reaction. The first step, namely the nucleophilic attack of the sp(2)-hyb...

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Detalles Bibliográficos
Autores principales: Cossío, Fernando P., de Cózar, Abel, Sierra, Miguel A., Casarrubios, Luis, Muntaner, Jaime G., Banik, Bimal K., Bandyopadhyay, Debasish
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8978721/
https://www.ncbi.nlm.nih.gov/pubmed/35424513
http://dx.doi.org/10.1039/d1ra06114c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8978721/
https://www.ncbi.nlm.nih.gov/pubmed/35424513
http://dx.doi.org/10.1039/d1ra06114c

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