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Role of imine isomerization in the stereocontrol of the Staudinger reaction between ketenes and imines
Computational–experimental analysis has allowed determining that the stereochemistry of the Staudinger reaction between ketenes and imines is strongly associated with the nature of the imine, which affects the two steps of the reaction. The first step, namely the nucleophilic attack of the sp(2)-hyb...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8978721/ https://www.ncbi.nlm.nih.gov/pubmed/35424513 http://dx.doi.org/10.1039/d1ra06114c |