Kinetic studies on Lewis acidic metal polyesterification catalysts – hydrolytic degradation is a key factor for catalytic performance

Kinetic analysis of polyesterification reactions using Lewis-acidic metal catalysts have been performed. While Sn-based catalysts are superior to Ti-based catalysts under neat polycondensation conditions (high [H(2)O]), the result is inverted under azeotropic conditions (low [H(2)O]). These findings...

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Detalles Bibliográficos
Autores principales: Wolzak, Lukas A., van Gemert, Rogier, van den Berg, Keimpe J., Reek, Joost N. H., Tromp, Moniek, Korstanje, Ties J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8978806/
https://www.ncbi.nlm.nih.gov/pubmed/35444794
http://dx.doi.org/10.1039/d1cy02306c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8978806/
https://www.ncbi.nlm.nih.gov/pubmed/35444794
http://dx.doi.org/10.1039/d1cy02306c

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