Cargando…
Kinetic studies on Lewis acidic metal polyesterification catalysts – hydrolytic degradation is a key factor for catalytic performance
Kinetic analysis of polyesterification reactions using Lewis-acidic metal catalysts have been performed. While Sn-based catalysts are superior to Ti-based catalysts under neat polycondensation conditions (high [H(2)O]), the result is inverted under azeotropic conditions (low [H(2)O]). These findings...
Autores principales: | Wolzak, Lukas A., van Gemert, Rogier, van den Berg, Keimpe J., Reek, Joost N. H., Tromp, Moniek, Korstanje, Ties J. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8978806/ https://www.ncbi.nlm.nih.gov/pubmed/35444794 http://dx.doi.org/10.1039/d1cy02306c |
Ejemplares similares
-
Mechanistic elucidation of monoalkyltin(iv)-catalyzed esterification
por: Wolzak, Lukas A., et al.
Publicado: (2021) -
Spectroscopic Investigation of the Activation of a
Chromium-Pyrrolyl Ethene Trimerization Catalyst
por: Venderbosch, Bas, et al.
Publicado: (2018) -
Ruthenium PNN(O) Complexes: Cooperative Reactivity and Application as Catalysts
for Acceptorless Dehydrogenative Coupling Reactions
por: de Boer, Sandra Y., et al.
Publicado: (2017) -
A coating from nature
por: Hermens, Johannes G. H., et al.
Publicado: (2020) -
Asymmetric Hydroformylation Using a Rhodium Catalyst Encapsulated in a Chiral Capsule
por: Jongkind, Lukas J., et al.
Publicado: (2020)