Synthesis of unprotected glyco-alkynones via molybdenum-catalyzed carbonylative Sonogashira cross-coupling reaction

Herein we report a novel Mo-catalyzed carbonylative Sonogashira cross-coupling between 2-iodoglycals and terminal alkynes. The reaction displays major improvements compared to a related Pd-catalyzed procedure previously published by our group, such as utilizing unprotected sugar derivatives as start...

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Detalles Bibliográficos
Autores principales: Darbem, Mariana P., Esteves, Henrique A., Burrow, Robert A., Soares-Paulino, Antônio A., Pimenta, Daniel C., Stefani, Hélio A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8979075/
https://www.ncbi.nlm.nih.gov/pubmed/35425248
http://dx.doi.org/10.1039/d1ra08388k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8979075/
https://www.ncbi.nlm.nih.gov/pubmed/35425248
http://dx.doi.org/10.1039/d1ra08388k

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