Cargando…
Theoretical investigation on the effect of the ligand on bis-silylation of C(sp)–C(sp) by Ni complexes
Density functional theory is used to study the bis-silylation of alkyne catalysed by a transition metal nickel–organic complex. The active catalyst, organic ligand, reaction mechanism, and rate-determining step were discussed with regard to dynamics and thermodynamics. COD or SIPr (COD = cyclooctadi...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8979076/ https://www.ncbi.nlm.nih.gov/pubmed/35425119 http://dx.doi.org/10.1039/d1ra08153e |