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Stepwise synthesis of a Zr–C–Si main chain polymer precursor for ZrC/SiC/C composite ceramics
Novel polymers containing a refractory metal in the main chain are highly desired as ultra-high temperature ceramic precursors. Herein, a low oxidation state active species Cp(2)Zr(ii) with two semi-filled outer orbits was firstly obtained using Cp(2)ZrCl(2) with Mg. This active species of Cp(2)Zr(i...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8979093/ https://www.ncbi.nlm.nih.gov/pubmed/35425217 http://dx.doi.org/10.1039/d1ra07783j |